四硫富瓦烯
共价键
材料科学
格子(音乐)
导电体
共价有机骨架
化学
分子
有机化学
物理
复合材料
声学
作者
Shangbin Jin,Tsuneaki Sakurai,Tim Kowalczyk,Sasanka Dalapati,Fei Xu,Hao Wei,Xiong Chen,Jia Gao,Shu Seki,Stephan Irle,Donglin Jiang
标识
DOI:10.1002/chem.201490189
摘要
Ordered tetrathiafulvalene structures are constructed by integrating into the lattice of 2D covalent organic frameworks. The tetrathiafulvalene columnar π-arrays offer pathways for high-rate hole transport, determine the frontier orbit levels, and upon oxidation form organic salts that exhibit drastically improved electric conductivity by several orders of magnitude. For more details, see the Communication by D. Jiang et al. on page 14608 ff.
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