克莱森重排
化学
乙烯基醚
烯丙基重排
卡罗尔重排
乙醚
有机化学
催化作用
药物化学
共聚物
聚合物
作者
Hidetoshi Tokuyama,Takaki Makido,Toshihiro Ueda,Tohru Fukuyama
标识
DOI:10.1081/scc-120002696
摘要
A protocol for one-pot Claisen rearrangement with n-butyl vinyl ether is described. Upon heating allylic alcohols with excess n-butyl vinyl ether with catalytic amount of Hg(OAc)2 and NaOAc, Claisen rearrangement takes place through in situ formation of the requisite allyl vinyl ether.
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