双原子分子
玻尔兹曼方程
玻尔兹曼常数
物理
分子
直接模拟蒙特卡罗
原子物理学
化学
经典力学
热力学
量子力学
蒙特卡罗方法
数学
统计
动态蒙特卡罗方法
摘要
A classical Boltzmann equation and collision integral of a gas of nonvibrating diatomic molecules is developed. It is shown that the generalization of the usual equation for structureless particles involves additional integrations over the angular momentum vector of the second molecule and two angles associated with the phases of the rotational motion of the two molecules. These latter angles are constants of the free motion of the molecules defined in a manner analogous to that of the usual impact parameter, i.e., they are determined by the free molecule trajectory as extrapolated to the point of closest approach.
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