化学
脱氢
甲酸
钳子运动
催化作用
同种类的
无机化学
二氧化碳
氢
组合化学
有机化学
热力学
物理
作者
Irene Mellone,Nikolaus Gorgas,Federica Bertini,Maurizio Peruzzini,Karl Kirchner,Luca Gonsalvi
出处
期刊：Organometallics
[American Chemical Society]
日期：2016-09-22
卷期号：35 (19): 3344-3349
被引量：77
标识
DOI：10.1021/acs.organomet.6b00551
摘要
Fe(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild reaction conditions.
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