钝化
材料科学
钙钛矿(结构)
能量转换效率
化学工程
量子点
量子效率
胺气处理
光电子学
纳米技术
图层(电子)
有机化学
化学
工程类
作者
Chong Chen,Fumin Li,Laipan Zhu,Zhitao Shen,Yujuan Weng,Qiang Lou,Furui Tan,Gentian Yue,Qingsong Huang,Mingtai Wang
出处
期刊:Nano Energy
[Elsevier]
日期:2020-02-01
卷期号:68: 104313-104313
被引量:58
标识
DOI:10.1016/j.nanoen.2019.104313
摘要
The defects in perovskite crystals and the penetration of moisture/oxygen into the perovskite layer are major problems for perovskite solar cells (PSCs) to achieve long-term stability and high power conversion efficiency (PCE). However, there is still a lack of multifunctional passivation materials to solve these problems. Herein, for the first time, we report oleyl amine-coated PbSO4(PbO)4 quantum-dots (QDs), as a passivation material with dual functions to simultaneously passivate the surface defects and block the penetration of moisture/oxygen into the perovskite layer for stable and efficient PSCs. The PbSO4(PbO)4 QDs significantly reduce the defect density of the as-prepared CH3NH3PbI3 films by passivating under-coordinated Pb ions and I anions and effectively enhance charge extraction efficiency at the TiO2/CH3NH3PbI3 and CH3NH3PbI3/spiro-OMeTAD interfaces. Moreover, the hydrogen bond between H atoms of the OA and I atoms of the perovskite and the interface electric field at CH3NH3PbI3/OA interface also contribute to the improvement of efficiency and stability of PSCs. Finally, higher PCE (20.02%) is achieved by the PSCs with OA-coated PbSO4(PbO)4 QDs compared to that (16.86%) of the PSCs without OA-coated PbSO4(PbO)4, corresponding to a 18.7% enhancement. Moreover, the PSCs with OA-coated PbSO4(PbO)4 QDs maintain 90% of initial efficiency after operation for 280 h, indicating better stability than the PSCs without PbSO4(PbO)4 QDs.
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