Transparent glass ceramics was obtained by heat-treating in 90TeO 2 -10Na 2 O glass. 2.7 μm emission of Er 3+ ions in the glass and glass ceramics matrix has been tested and compared, and the results suggest that nucleation is a possible way to enhance 2.7 μm emission. Er 3+ ions were embedded into the nano-crystals (Er 2 Te 5 O 13 and Er 6 Te 5 O 19.2 ) evidenced by X-ray powder diffraction (XRD) spectra and the crystal size was calculated by Debye-Scherrer formula.