乙酰丙酸
乙腈
化学
氧化还原
二甲基亚砜
电化学
水溶液
丙酮
无机化学
溶剂
有机溶剂
亚砜
有机化学
催化作用
电极
化学工程
物理化学
工程类
出处
期刊:Журнал Сибирского федерального университета
[Siberian Federal University]
日期:2021-09-01
卷期号:14 (3): 388-395
被引量:3
标识
DOI:10.17516/1998-2836-0246
摘要
The redox properties of levulinic acid (LA) were studied by electrochemical methods in acetonitrile, a mixture of acetonitrile with water, ethanol, acetone, and dimethyl sulfoxide. It was shown that the irreversible two-electron reduction of LA under the studied conditions leads to the formation of γ-valerolactone. This reduction potential depends on the solvent and shifted anodically by following order: dimethyl sulfoxide
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