DMF‐Mediated Diffusion Regulation in Pyridine–Carboxylate Metal–Organic Frameworks Enables Efficient CHF 3 Capture

and sustaining excellent separation even at 60%RH. Notably, PAIF-101 can be rapidly synthesized in scalable quantities via a simple reflux method, yielding around 5 grams per batch. Taken together, the outstanding separation performance, robust stability, and scalable synthesis of PAIF-101 demonstrate its great potential for this challenging industrial separation.