化学
氮氧化物
催化作用
X射线光电子能谱
漫反射红外傅里叶变换
X射线吸收精细结构
选择性催化还原
傅里叶变换红外光谱
红外光谱学
光化学
氧气
原位
无机化学
光谱学
有机化学
化学工程
光催化
燃烧
工程类
物理
量子力学
作者
Ruoyuan Li,Aixia Li,Junhua Li,Yao Wang,Zhiming Liu
标识
DOI:10.1016/j.jcat.2024.115336
摘要
Selective catalytic reduction of NOx by CO (CO-SCR) in the presence of O2 is challenging because in this process CO is prone to being oxidized by O2, thus inhibiting NOx reduction by CO. Furthermore, SO2 typically leads to the deactivation of the CO-SCR catalyst. Herein, a significant promoting effect of SO2 on Ir/SiO2 catalyst for the CO-SCR of NOx in the presence of O2 is reported. In-situ X-ray Absorption Fine Structure (XAFS) and X-ray photoelectron spectroscopy (XPS) analysis showed that SO2 does not affect the chemical nature of Ir0 under reaction conditions. However, SO2 can be oxidized to sulfate and deposit on the catalyst surface. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analysis demonstrated that the presence of SO2 can inhibit the CO + O2 reaction, thus leaving more CO available to reduce NOx over the active Ir0 sites. As a result, the reduction of NOx is remarkably promoted even in the presence of O2 and SO2.
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