过电位                        
                
                                
                        
                            催化作用                        
                
                                
                        
                            硼酸                        
                
                                
                        
                            氢                        
                
                                
                        
                            硼                        
                
                                
                        
                            无机化学                        
                
                                
                        
                            材料科学                        
                
                                
                        
                            化学工程                        
                
                                
                        
                            双金属片                        
                
                                
                        
                            制氢                        
                
                                
                        
                            箔法                        
                
                                
                        
                            化学                        
                
                                
                        
                            电化学                        
                
                                
                        
                            电极                        
                
                                
                        
                            复合材料                        
                
                                
                        
                            有机化学                        
                
                                
                        
                            物理化学                        
                
                                
                        
                            工程类                        
                
                        
                    
            作者
            
                Yao Zhang,Fengxin Cao,Wenjing Wang,Yan Zhang,Zhikang Yang,Qiaoling Li,Chengzhong Yu            
         
                    
        
    
            
            标识
            
                                    DOI:10.1016/j.mcat.2023.113670
                                    
                                
                                 
         
        
                
            摘要
            
            Hydrogen is a vital clean energy, and reducing overpotential in hydrogen evolution has become necessary research, in which CoMo bimetal material is a promising high-efficiency hydrogen evolution material. In this study, boron was added to MoCo bimetallic ion catalysts with carbon cloth and copper foil substrates, and it was found that adding boron could significantly reduce the hydrogen evolution overpotential of the catalysts. The morphology analysis by SEM showed that the addition of boric acid in the electrolyte could change the morphology of the catalyst, making the surface of the catalyst smooth and uniform distribution on the carrier, while the surface of the catalyst without boric acid formed agglutination. The prepared CoMoB-CC catalyst has an overpotential of 44.1 mV when the current density is -10 mA·cm−2. This paper primarily presents interesting phenomenon of the smooth effect of boric acid on the catalytic electrode, and the prepared catalyst has good catalytic performance, which provides some help for the preparation of hydrogen evolution materials.
         
            
 
                 
                
                    
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