串联
钙钛矿(结构)
带隙
材料科学
硅
温度系数
钙钛矿太阳能电池
光电子学
太阳能电池
晶体硅
结晶学
化学
复合材料
作者
Ahmad Halal,Balázs Plesz
标识
DOI:10.1109/therminic60375.2023.10325899
摘要
Monolithic Perovskite/Si tandem solar cells represent a promising direction in photovoltaic technology. However, understanding the temperature coefficient is essential for predicting performance and improving the temperature adaptability of these devices under varying weather conditions. This paper conducts a detailed analysis of the thermal behavior of c-Si as a bottom cell in a monolithic Perovskite/Si tandem arrangement, exploring how its behavior differs from standalone configurations. This investigation is carried out through a numerical simulation using SCAPS software. The simulation considers the temperature-dependent bandgap and absorption for both c-Si and perovskite, as well as the temperature effects on series and shunt resistances. Four simulation scenarios were analyzed, 1) as a standalone c-Si solar cell, 2) c-Si bottom cell in perovskite/Si tandem structure with spectrum split at the perovskite bandgap, 3) c-Si bottom cell, considering perovskite temperature-dependent bandgap, and 4) c-Si bottom cell, considering perovskite layer thickness, absorption and its temperature-dependent bandgap. The results reveal that c-Si solar cells in tandem structures experience notable differences in temperature coefficients, especially in the short-circuit and MPP current densities, compared to standalone configurations. This difference is mainly attributed to the spectrum splitting and temperature-dependent perovskite absorption. Splitting the spectrum leads to an increase in the temperature coefficient of J SC from 0.0944% °C −1 to 0.2539% °C −1 ; this temperature coefficient reached 0.983% °C −1 when the top cell layer thickness and perovskite's temperature-dependent bandgap and absorption were incorporated into the analysis. Nevertheless, only a minor variation was observed in the voltage temperature coefficient, for both in standalone c-Si cells and those incorporated as bottom cells in the tandem structure.
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