Vivianite for Phosphorus Recovery from Digester Supernatant in Wastewater Treatment Plants

Abstract Phosphorus (P) recovery by crystallization of vivianite in digester supernatant (DS) was investigated. A high recovery yield (> 90 %) was obtained with vivianite even for DS with low P concentration (74 mg L−1), as opposed to the formation of struvite and hydroxyapatite where the yield was lower than 50–60 %. Various strategies were tested to produce vivianite with large sizes and narrow size distribution, such as a controlled reagent dosing profile, self‐seeded crystallization, and multistage cascade‐seeded crystallization. The obtained results demonstrated that the main challenge in the development of vivianite P recovery is to promote crystal growth and to suppress secondary nucleation of vivianite during the crystallization process.