光催化
分解水
光催化分解水
制氢
动能
硫化物
限制
铟
材料科学
纳米技术
航程(航空)
化学工程
工艺工程
化学
氢
催化作用
物理
工程类
光电子学
机械工程
复合材料
生物化学
有机化学
量子力学
冶金
作者
Jun Qiang,Hailing Huo,Chengxi Huang,Tongyu Wang,Xuan Li,Zhenzhen Liang,Liang Zhang,Jingjing Ma,Erjun Kan,Ang Li
标识
DOI:10.1016/j.ces.2023.119507
摘要
Photocatalytic overall water splitting (OWS) for H2 and H2O2 production without sacrificial agents is an appealing strategy to realize solar energy conversion. In order to realize photocatalytic OWS, it is necessary for materials to simultaneously satisfy thermodynamic and kinetic requirements, limiting the available selection scope of materials. Therefore, unlocking the potential of these materials that partially fulfill the requirements for photocatalytic overall water splitting would significantly expand the range of material choices. Here, taking In2S3 as an example, we successfully unlocked the OWS potential through a size-dependent strategy, which is based on quantum confinement effect. By adjusting its size to 2.25 nm, it can exhibit impressive photocatalytic OWS activity with the H2 and H2O2 generation rate of ∼42.17 μmol∙g−1∙h−1 and ∼38.65 μmol∙g−1∙h−1, respectively. This work provides a simple strategy to expand the range of materials selection for H2 and H2O2 production from photocatalytic OWS.
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