胶体
化学
土壤水分
环境化学
金属
氧化还原
纳米颗粒
有机质
水溶液
粒径
氢氧化物
作文(语言)
无机化学
化学工程
地质学
土壤科学
物理化学
工程类
有机化学
语言学
哲学
作者
Xinyang Li,Zhenyu Cao,Yanpei Du,Yu Zhang,Jiajia Wang,Xingmao Ma,Pengjie Hu,Yongming Luo,Longhua Wu
标识
DOI:10.1016/j.jhazmat.2023.132684
摘要
Naturally-occurring colloids and nanoparticles are crucial in transporting heavy metal contaminants in soil-water systems. However, information on particle-bound metals’ size distribution and elemental composition in paddy soils under redox-fluctuation is scarce. Here, we investigated the mobilization of Cu, Cd, and Pb-containing nanoparticles and colloids in four contaminated soils with distinctive geochemical properties during reduction and subsequent re-oxidation. Using AF4-UV-ICP-MS and STEM-EDS, we observed that particle-bound metals were primarily associated with two sizes ranges: 0.3−40 kDa (F1) and 130 kDa−450 nm (F2), which mainly consisted of organic matter (OM), iron hydroxide and clay minerals. Cu and Pb were more likely bound to colloid than Cd. Colloidal Cu, Pb and Cd accounted for averages of 83.2%, 72.4% and 19.8% of their total concentration in solution (<0.45 µm) during soil reduction, and decreased during soil re-oxidation. This proportion was also positively correlated with aqueous pH and DOC but negatively correlated with Eh. Further quantitative analysis demonstrated that Cu/Cd positively correlated with OM at nanometric scale (F1). This study provides quantitative insights into the size, composition and abundance of polymetallic pollutant-carrying particles in paddy soils during redox fluctuation, and highlights the importance of nanometric interactions between OM and toxic cationic metals for their release.
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