Alginate composite films incorporated with Zn‐based inorganic antimicrobials for food packaging: Effects of morphology

Biopolymers-based food packaging materials have drawn attention as potential candidates for substitution of petroleum-based materials. In this study, composite alginate films were developed by incorporating Zn-based antimicrobials to overcome the intrinsic disadvantages of alginates that hinder their wide applications. Antimicrobials with different morphologies (nanoplatelets, nanorods, and nanospheres) were employed to investigate the effects of antimicrobials' morphology on antibacterial, thermal, mechanical, and barrier performance of composite alginate films. Meanwhile, morphological and structural characterizations were carried out to explore the interactions between antimicrobials and alginate matrix. Results indicated that films with nanospheres exhibited superior antibacterial property, while those with one-dimensional nanorods possessed better mechanical and barrier performance. Besides, preliminary test on fresh-cut potatoes and chicken breasts indicated that the composite films showed potential in extending shelf life of foods. By incorporating antimicrobials with three different morphologies, this study provides particular insights into improving properties of composite packaging materials.