材料科学
钾
石墨烯
化学工程
纳米颗粒
纳米技术
离子
化学
冶金
有机化学
工程类
作者
Jing Li,Feng Hu,Hui Wei,Jinpei Hei,Yueping Yin,Guoan Liu,Nannan Wang,Hehe Wei
标识
DOI:10.1016/j.compositesb.2022.110424
摘要
Benefiting from the unique layer structure and large interlayer spacing, the transition metal dichalcogenides have been regarded as promising anode materials to host K ions and widely explored in potassium ion batteries (PIBs). However, the low conductivity and large volume variation decline the cycling capacity and stability. It is still challenge to develop high performance anode to storage K + . Herein, the MoS 2 nanoparticles anchored onto graphene sheet were synthesized (MoS 2 –C/rGO) through facile “one-step redox reaction” and following sulfidation method. Impressively, MoS 2 –C/rGO displayed superb cycling capability with a high reversible capacity of 405.25 mAh/g after 100 cycles at 0.1 A/g, accompanied with remarkable rate performance, outperforming than MoS 2 –C and MoS 2 . Most importantly, the ultra-long working life over 2000 cycles with a stable capacity of 161.67 mAh/g at 2 A/g was achieved in MoS 2 –C/rGO. The two-dimensional structure, rGO sheet and N, P co-doped C matrix of MoS 2 –C/rGO play great role on providing abundant ions storage sites, increasing conductivity and suppressing volume expansion, leading to high specific capacity, superior rate performance and cycling stability in PIBs. The ex-situ XPS revealed the conversion reaction mechanism for MoS 2 during cycling. Accordingly, our work provides a new insight to design alternative anodes for PIBs and is significant to the application of the new generation secondary batteries. • The MoS 2 nanparticles mixed with N, P co-doped C matrix were confined on to the graphene sheet unifromly. • The ultra-long life span over 2000 cycles in high rate of 2 A/g with a high reversible capacity was achieved. • The sheet-like structure and superior effect of carbonaceous materials leads to remarkable potassium ion batteries performance. • The ex-situ XPS results verifies the reversible reaction and conversion mechanisms during potassiation/depotassiation process.
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