膜
化学工程
材料科学
过滤(数学)
涂层
界面聚合
纳米纤维
原位聚合
溶剂
聚合
环境友好型
水处理
色谱法
聚合物
化学
复合材料
纳米技术
有机化学
废物管理
单体
统计
数学
生物化学
工程类
生态学
生物
作者
Dukjoon Kim,Bhandari Subash Chandra,Anima Bose
标识
DOI:10.1016/j.jece.2023.110560
摘要
Here we report on the successful super-oleophobic membrane, a key approach to improving the reusable oil-water separation with high water flux abilities avoiding the critical drawbacks of super-oleophilic membranes such as oil-retention and low water flux. In the development, we used a durable hydrophilic-based PVDF membrane modified by sulfonated polydopamine via the in-situ polymerization method using an eco-friendly solvent, ethanol. In this study, an ultra-thin sulfonated polydopamine (SPD) layer was coated onto PVDF nanofiber creating PVDF-SPD by varying coating time for obtaining improved super-hydrophilic membrane. The final 24 h in-situ polymerized coated membrane, PVDF-SPD24h exhibited excellent oil/water separation performed with 36,000 Lm−2h−1 of water flux and 99% of separation efficiency. It remains at ∼97.8% of separation efficiency even after 30 filtration recycles with test mixture. In addition, the PVDF-SPD24h membrane also demonstrated relevant performance in harsh acid and alkaline media with less than 3 wt% of weight loss after 48 h of treatment at 80 °C. These results suggest that PVDF-SPD24h could be sustainable membrane for oily wastewater treatment purposes.
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