纳米结构
化学工程
锂(药物)
电极
石墨烯
X射线光电子能谱
氧化物
储能
电导率
纳米晶
电化学
材料科学
纳米技术
化学
冶金
物理
工程类
内分泌学
物理化学
功率(物理)
医学
量子力学
作者
Dongdong Zhang,Qingyi Wei,Haili Huang,Lan Jiang,Jie Teng,Ruizhi Yu,Qing Zhang,Shengxing Liu,Lin Wang,Weiyou Yang
出处
期刊:Energy & environmental materials
日期:2023-02-07
被引量:1
摘要
Crystalline γ‐Ga 2 O 3 @rGO core–shell nanostructures are synthesized in gram scale, which are accomplished by a facile sonochemical strategy under ambient condition. They are composed of uniform γ‐Ga 2 O 3 nanospheres encapsulated by reduced graphene oxide (rGO) nanolayers, and their formation is mainly attributed to the existed opposite zeta potential between the Ga 2 O 3 and rGO. The as‐constructed lithium‐ion batteries (LIBs) based on as‐fabricated γ‐Ga 2 O 3 @rGO nanostructures deliver an initial discharge capacity of 1000 mAh g −1 at 100 mA g −1 and reversible capacity of 600 mAh g −1 under 500 mA g −1 after 1000 cycles, respectively, which are remarkably higher than those of pristine γ‐Ga 2 O 3 with a much reduced lifetime of 100 cycles and much lower capacity. Ex situ XRD and XPS analyses demonstrate that the reversible LIBs storage is dominant by a conversion reaction and alloying mechanism, where the discharged product of liquid metal Ga exhibits self‐healing ability, thus preventing the destroy of electrodes. Additionally, the rGO shell could act robustly as conductive network of the electrode for significantly improved conductivity, endowing the efficient Li storage behaviors. This work might provide some insight on mass production of advanced electrode materials under mild condition for energy storage and conversion applications.
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