Highly N‐Doped Fe/Co Phosphide Superstructures for Efficient Water Splitting

Abstract Developing an inexpensive bifunctional electrocatalyst for overall water splitting is critical for acquiring scalable green hydrogen and thereby realizing carbon neutralization. Herein, an “all‐in‐one” method is developed for the fabrication of highly N‐doped binary FeCo‐phosphides (N‐FeCoP) with hierarchical superstructure, this delicately designed synthesis route allows the following merits for benefiting water splitting electrocatalysis in alkaline, including high N/defect‐doping for mediating the surface property of the as‐made N‐FeCoP, binary Fe and Co components exhibiting strong coupling interaction, and 3D hierarchical superstructure for shortening diffusion length and thereby improving reaction kinetics. Electrochemical measurements reveal that the N‐FeCoP sample exhibits very low overpotentials for initiating the hydrogen and oxygen evolution reactions. Remarkably, overall water splitting can be promoted on N‐FeCoP using a commercial primary Zn‐MnO 2 battery. The developed synthesis strategy may potentially inspire the preparation of other N‐doped metal‐based nanostructures for broad electrocatalysis.