MWCNTs/polyimide multilayered aerogel-based paper enabling high-temperature-resistant and flexible sensor

In recent years, as the electronics industry has driven the development of human civilization, flexible responsive materials have become highly favored in sensing applications. However, most flexible materials are not stable under high-temperature conditions, so only a few flexible responsive materials are suitable for high-temperature and high-strength applications. In this paper, multi-walled carbon nanotubes (MWCNTs) were added as conductive material into poly(amic acid) ammonium salt (PAAS) solutions to prepare MWCNTs/polyimide aerogel-based papers (CPs) by a simple method. The introduction of MWCNTs into the ordered multilayer folded structure of the CPs provided a conductive pathway and improved their thermal stability. When the multilayer folded structure was deformed, the MWCNTs between the layers contacted each other, increasing the number of electron transport channels and providing a larger contact area for the conductive network. When the deformation was removed, the MWCNTs in the interlayer contact zone rapidly separated, providing stable and excellent responsiveness at high temperatures (CP-2: ΔR/R0 value of up to −0.45 at 300 °C) and favorable stability after 1000 cycles (CP-2: RV retention of 92.4 % at 25 °C and 80.5 % at 300 °C). Therefore, the prepared CPs have great application prospects in the fields of high-temperature mechanical device monitoring, sensing, and alarms.