铍
氧化态
化学
分子
二聚体
配体(生物化学)
计算化学
组合化学
无机化学
有机化学
金属
生物化学
受体
作者
Shannon A. Couchman,Nicole Holzmann,Gernot Frenking,David J. Wilson,Jason L. Dutton
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2013-01-01
卷期号:42 (32): 11375-11375
被引量:104
摘要
A theoretical study of compounds containing Be in the +1 or 0 oxidation state has been carried out. The molecules considered containing Be in the +1 oxidation state are analogues of the important Mg(I)–Mg(I) dimer supported by the β-diketiminate ligand. The molecules in the 0 oxidation state are NHC supported compounds analogous to “molecular allotropes” which has recently become a topic of importance in p-block chemistry. In this case, our results demonstrate that the Be(0) complexes are far more stable than the analogous Mg(0) complexes, highlighting the opportunities afforded in Be chemistry, despite the challenges presented by the toxicity of Be compounds.
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