拉尼奥
非阻塞I/O
催化作用
解吸
合成气
二氧化碳重整
蒸馏水
程序升温还原
甲烷
钙钛矿(结构)
材料科学
降水
核化学
无机化学
化学
化学工程
矿物学
吸附
结晶学
物理化学
有机化学
气象学
电介质
工程类
物理
铁电性
光电子学
色谱法
作者
Maryam Mousavi,Ali Nakhaei Pour,Mostafa Gholizadeh,Ali Mohammadi,Seyed Mehdi Kamali Shahri
摘要
Abstract BACKGROUND The dry reforming of methane (DRM) process has received considerable attention for the production of syngas owing to its great environmental and economic benefits. LaNiO 3 and La 0.5 Sr 0.5 NiO 3 nanoparticles were synthesized with the co‐precipitation procedure using distilled and magnetic distilled water, and examined as catalysts in DRM. RESULTS The structure and morphology of the prepared nanoparticles were characterized by X‐ray diffraction, the Brunauer–Emmett–Teller method, scanning and transmission electron microscopy, and temperature‐programmed reduction, desorption and hydrogenation techniques. The experimental results proved that the treated La 0.5 Ni 0.5 SrO 3 catalyst had better initial performance in DRM in comparison with the LaNiO 3 catalyst, due to its greater surface basicity. The orientation for deposition of carbon over the surface of the consumed catalysts was as follows: La 0.5 Sr 0.5 NiO 3 treated > La 0.5 Sr 0.5 NiO 3 non‐treated > LaNiO 3 non‐treated > LaNiO 3 treated . CONCLUSION Among the synthesized catalysts, the treated La 0.5 Sr 0.5 NiO 3 sample exhibited higher initial DRM activity, due to its greater surface basicity. Also, the higher surface basicity of the strontium‐substituted catalyst led to an increase in CO 2 desorption and coke deposition according to the Boudouard reaction. © 2020 Society of Chemical Industry
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