结晶度
太阳能电池
钙钛矿(结构)
材料科学
化学工程
能量转换效率
钙钛矿太阳能电池
结晶
碳纤维
粒度
Crystal(编程语言)
电极
带隙
热稳定性
矿物学
化学
光电子学
复合材料
物理化学
程序设计语言
工程类
复合数
计算机科学
作者
Chong Liu,Miao Wu,Yuanchuang Wu,Duofa Wang,Tianjin Zhang
标识
DOI:10.1016/j.jpowsour.2019.227389
摘要
The all-inorganic CsPbI2Br shows potential applications in perovskite solar cell owning to the reasonable band gap and superior thermal stability. However, the power conversion efficiency is rather low comparing to the organic-inorganic hybrid perovskite solar cell, which is mainly induced by the inferior crystal quality. In this paper, we investigate the crystallization kinetics of CsPbI2Br perovskite film and find that the intermediate CsBr is easily formed due to its low solubility, which affects the crystalline quality of CsPbI2Br film. Employment of over-stoichiometric lead reactant (PbI2, PbBr2) or adding other lead-containing compound (PbCl2, Pb(SCN)2) effectively suppress the production of the intermediate CsBr and result in much improved crystallinity of CsPbI2Br, with a grain size of several micrometers. Accordingly, the CsPbI2Br solar cell with carbon electrode shows a stable and high power conversion efficiency of 12.19%, comparing to 9.50% of the control cell.
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