阳极
石墨
电解质
阴极
锂(药物)
电池(电)
材料科学
容量损失
电极
充电周期
离子
化学工程
复合材料
化学
热力学
功率(物理)
物理
内分泌学
物理化学
有机化学
工程类
医学
涓流充电
作者
Teiji Watanabe,Takashi Tsuda,Nobuo Ando,Susumu Nakamura,Narumi Hayashi,Naohiko Soma,Takao Gunji,Takeo Ohsaka,Futoshi Matsumoto
标识
DOI:10.1016/j.electacta.2019.134848
摘要
In order to actually compensate “an irreversible capacity (i.e., an active lithium loss) ˮ usually observed at the 1st charging/discharging cycle of lithium ion batteries (LIBs), e.g., caused by a solid-electrolyte interphase (SEI) formation, a so-called pre-lithiation was applied to the graphite anodes of the laminated cell composed of three graphite anodes and three LFP (lithium iron phosphate) cathodes which were through-holed with the hole diameter of 20, 100 or 200 μm like the squares of a “Go-board”. The pre-lithiation was carried out (keeping an appropriate pre-lithiation charge amount) firstly by directly contacting the anodes with Li metal, which was previously introduced in the cell, to intercalate Li+ ions to them and then conducting the capacity balancing among the Li+-intercalated anodes by contacting them for a various period of time. It was found that in the cell composed of the through-holed anodes and cathodes with a given hole diameter the irreversible capacity can be significantly reduced by appropriately choosing the pre-lithiation charge amount and the capacity balancing time. Typically, in the anodes (the hole diameter: 20 μm) with the total capacity of 35 mAh, when the pre-lithiation charge amount was 3 mAh and the capacity balancing time was 12 h, no irreversible capacity could be observed actually, i.e., the 1st charge capacity was close to 100% and the expected stable charge/discharge capacities were obtained with the capacity retention of almost 100% in the continuous charge/discharge cycle. The results obtained demonstrate that the pre-lithiation of LIBs can be significantly improved using through-holed anodes and cathodes.
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