电池(电)
阳极
材料科学
电镀
电解质
动能
纳米技术
金属
电化学
扩散
扩散限制聚集
化学物理
航程(航空)
化学工程
冶金
电极
分形
化学
分形维数
热力学
复合材料
工程类
功率(物理)
物理化学
数学分析
物理
量子力学
数学
图层(电子)
作者
Janna Eaves-Rathert,Kathleen Moyer,Murtaza Zohair,Cary L. Pint
出处
期刊:Joule
[Elsevier]
日期:2020-06-01
卷期号:4 (6): 1324-1336
被引量:98
标识
DOI:10.1016/j.joule.2020.05.007
摘要
Until now, a key barrier toward realizing a high energy density Mg2+ battery has been the limited understanding of mechanisms governing multivalent metal electrodeposition. This, compounded with recent observations of Mg dendrites, highlights the need for better fundamental insight into multivalent systems. We present a comprehensive study of electrodeposition in practical coin-cell configurations to evaluate the mechanisms of growth from common Mg(TFSI)2-based electrolytes. Our findings indicate a transition from charge-transfer-limited to diffusion-limited electrodeposition processes that govern the morphological evolution of Mg deposits. We observe the signature of cell shorting under a wide range of current densities that we attribute to 3D hemispherical growth of Mg deposits that form under mixed diffusion and kinetic control and are distinguished from traditional fractal dendrites. Our results highlight synergy with classical electrochemical theories for growth and lay groundwork for future approaches to achieve stable electroplated multivalent metal electrodes.
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