材料科学
钴
纳米颗粒
矫顽力
化学工程
合金
铁磁性
针状的
纳米结构
磁化
磁性纳米粒子
纳米技术
冶金
磁场
微观结构
物理
工程类
量子力学
凝聚态物理
作者
Subbiah Amsarajan,Balaji R. Jagirdar
标识
DOI:10.1016/j.jallcom.2019.152632
摘要
Phase pure Co7Fe3 alloy magnetic nanostructures were successfully synthesized by co-digestive ripening of Fe/Co-toluene nanoparticles in mesitylene in the presence of hexadecyl amine (HDA). Controlled heat treatment of as-synthesized samples under anaerobic conditions showed a transformation of disordered-to-ordered crystal structure, which was confirmed by PXRD and TEM measurements. This also resulted in carbonization of HDA over the nanoparticles surface rendering them air-stable. Magnetic measurements of these carbon-encased samples revealed enhanced saturation magnetization (MS) values compared to the as-prepared samples. The zero field cooling (ZFC) and field cooling (FC) curves demonstrated that Co7Fe3 nanoparticles exhibit ferromagnetic behaviour at room temperature. These air-stable Co–Fe magnetic nanostructures have immense potential for applications as soft magnets.
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