With ethyl methacrylate,butyl acrylate,2-hydroxy ethyl methacrylate,methacrylic acid 2,2,2-trifluoroethyl ester as the raw materials,fluoro-acrylate copolymer are prepared by solution polymerization.The hardness,adhesion,waterproofness,solvent resistance and surface performance are determined.The testing result indicates that the films made by fluoro-acrylate copolymer solution have better properties than those made by pure acrylate copolymer.