Contribution of soil erosion to PAHs in surface water in China

In China, the total annual atmospheric emission of 16 polycyclic aromatic hydrocarbons (PAHs) reach up to approximate 100 thousand tons, part of which is preserved in soils. In this study, the contribution of soil erosion to PAHs in surface water nationwide was quantified. The results indicate that a major portion of the annual PAHs emission is lost from soils via rainfall erosivity and subsequently transported to the ocean. The national annual flux of PAHs from soil to surface water by the natural physical forces of water measures up to ~70 thousand tons, which accounts for ~62% of the annual emission of PAHs with 19% entering the sea directly. In general, both the soil erosion intensity and flux of PAHs for the regions located in the Southeast of China are over those in the Northwest of China, with the regions being divided into two different parts by the famous geographic "Hu Huanyong line", reflecting the intensive impact of human activities on environmental degradation. Comparative analysis suggested that there must be a big fraction of PAHs lost during transmission due to the river sedimentation and lake dispersion. This study closes a major gap in the national budget of PAHs and provides critical information in the context of regional environment risk assessment. • Seventy kilotons of PAHs from soil to surface water by rainfall per year in China • About 19% of the total annual emission of PAHs enters the sea via soil erosion. • SEI and MTR in the Southeast of China are over those in the Northwest of China. • A big fraction of PAHs lost during mobilization from soils to the sea.