Strong influence of degree of substitution on carboxymethyl cellulose stabilized sulfidated nanoscale zero-valent iron

Carboxymethyl cellulose (CMC) has been widely adopted as stabilizer to enhance the subsurface mobility of nanoscale zerovalent iron (nZVI). However, CMC surface modification also cause severe decrease of the longevity and electron utilization efficiency (εe) of nZVI, which is still not well understood. In this study, we demonstrate the negative influence of CMC on the properties of sulfidated nZVI (S-nZVI) could be reversed by increasing the degree of substitution (D.S.) of CMC. Consistent with previous study, the sample CMC-S-nZVI prepared with commercial CMC with degree of substitution (D.S.) of 0.75 exhibited a considerable low longevity of 33 days with εe of 4.5%, much lower than that of sulfidated nZVI (S-nZVI, 113 days and 13%). In sharp contrast, the sample HCMC-S-nZVI synthesized with CMC with super high D.S. of 1.76 demonstrated significantly enhanced longevity of 139 days and εe of 20%. The enhancement was attributed to compatible molecular structure of CMC with super high D.S. Moreover, the HCMC-S-nZVI also exhibited higher mobility in porous media than CMC-S-nZVI. Our work provides a feasible way to prepare S-nZVI with desired properties including high subsurface transportability, high longevity and high εe.