插层(化学)
过渡金属
第2组金属有机化学
茂金属
衍射
无机化学
金属
结晶学
材料科学
化学
穆斯堡尔谱学
冶金
有机化学
分子
催化作用
聚合
物理
聚合物
光学
作者
Thomas R. Halbert,D. C. Johnston,L. E. McCandlish,A. H. Thompson,Joseph C. Scanlon,James A. Dumesic
出处
期刊:Physica
[Elsevier]
日期:1980-01-01
卷期号:99 (1-4): 128-132
被引量:29
标识
DOI:10.1016/0378-4363(80)90220-x
摘要
The syntheses of the new intercalate compounds FeOCl[(EtMe4Cp)2Fe]0.16, VOCl(CoCp2)0.16, and TiOCl(CoCp2)0.16 are reported. Their structures are found by X-ray powder diffraction to be qualitatively the same as those of the previously reported complexes FeOCl(CoCp2)0.16 and FeOCl(FeCp2)0.16. Results of 57Fe Mössbauer and magnetic susceptibility studies on the latter two compounds are reported, and shown to be consistent with electron transfer from the metallocene to the host upon intercalation.
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