化学
三正丁基氢化锡
钯
催化作用
氢化物
三丁基锡
氨基酸
组合化学
有机化学
生物化学
氢
作者
F. Guibé,Olivier Dangles,G. Balavoine
标识
DOI:10.1016/s0040-4039(00)84530-x
摘要
Allyl(All) and Allyloxycarbonyl(Alloc) amino-acid derivatives are deprotected through palladium-catalyzed hydrostannolysis by Bu3SnH in a highly selective manner. Benzyl and benzyloxycarbonyl groups are stable under these conditions. Moreover the allyl and Alloc groups seem orthogonal to the t-butyl and t-butoxycarbonyl protecting groups.
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