化学
高价分子
碘
哌啶
产量(工程)
小学(天文学)
亚胺
有机化学
腈
药物化学
催化作用
材料科学
物理
天文
冶金
作者
Robert M. Moriarty,Radhe K. Vaid,Michael P. Duncan,Masahito Ochiai,Minako Inenaga,Yoshimitsu Nagao
标识
DOI:10.1016/s0040-4039(00)88473-7
摘要
Primary aliphatic amines on oxidation with iodosobenzene in CH2Cl2 or H2O yield the corresponding nitriles, while primary cycloalkylamines give the corresponding cyclic ketones. Lactams are obtained by the oxidation of cyclic amines. (S)(−) Nicotine (15) is oxidized to (+)-cotinine (16). The intermediary imine involved in these processes was trapped in the case of piperidine as the α-aminonitrile.
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