化学
芳基
范围(计算机科学)
三氟甲磺酸
组合化学
碘
有机化学
催化作用
计算机科学
程序设计语言
烷基
作者
Marcin Bielawski,Mingzhao Zhu,Berit Olofsson
标识
DOI:10.1002/adsc.200700373
摘要
Abstract Symmetrical and unsymmetrical diaryliodonium triflates have been synthesized from both electron‐deficient and electron‐rich arenes and aryl iodides with m CPBA and triflic acid. A thorough investigation of the optimization, scope and limitations has resulted in an improved one‐pot protocol that is fast, high‐yielding, and operationally simple. The reaction has been extended to the direct synthesis of symmetrical iodonium salts from iodine and arenes, conveniently circumventing the need for aryl iodides.
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