Synthesis of (Ca,Mg)-α-sialon from slag by self-propagating high-temperature synthesis

The synthesis of (Ca,Mg)-α-sialon powders using slag as a starting material by self-propagating high-temperature synthesis (SHS) is reported for the first time. The only crystalline phase detected in the synthesized products was α-sialon. The characters of the synthesized powders were observed and compared with that of conventionally hot-pressed materials. More metal cations were absorbed into the α-sialon structure of the SHS synthesized powders. Fully densified sialon ceramics can be obtained using the SHS powders by hot-pressing. The hardness and fracture toughness of the hot-pressed α-sialon ceramics reached 16 GPa and 5.1 MPa m−1/2 respectively.