材料科学
铁磁性
算法
人工智能
物理
计算机科学
凝聚态物理
作者
B. Folkers,Thies Jansen,Thijs J. Roskamp,Pim Reith,André Timmermans,Daen Jannis,Nicolas Gauquelin,Johan Verbeeck,H. Hilgenkamp,Carlos M. M. Rosário
标识
DOI:10.1103/physrevmaterials.8.054408
摘要
${\mathrm{LaMnO}}_{3}$ (LMO) thin films epitaxially grown on ${\mathrm{SrTiO}}_{3}$ (STO) usually exhibit ferromagnetism above a critical layer thickness. We report the use of scanning SQUID microscopy (SSM) to study the suppression of the ferromagnetism in STO/LMO/metal structures. By partially covering the LMO surface with a metallic layer, both covered and uncovered LMO regions can be studied simultaneously. While Au does not significantly influence the ferromagnetic order of the underlying LMO film, a thin Ti layer induces a strong suppression of the ferromagnetism, over tens of nanometers, which increases with time on a timescale of days. Detailed electron energy loss spectroscopy analysis of the Ti-${\mathrm{LaMnO}}_{3}$ interface reveals the presence of ${\mathrm{Mn}}^{2+}$ and an evolution of the Ti valence state from ${\mathrm{Ti}}^{0}$ to ${\mathrm{Ti}}^{4+}$ over approximately 5 nm. Furthermore, we demonstrate that by patterning Ti/Au overlayers, we can locally suppress the ferromagnetism and define ferromagnetic structures down to sub-micrometer scales.
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