Pinpointing the Cl Coordination Effect on Mn‐N3‐Cl Moiety Toward Boosting Reaction Kinetics and Suppressing Shuttle Effect in Li–S Batteries

Abstract Single atom catalysts (SACs) are highly favored in Li–S batteries due to their excellent performance in promoting the conversion of lithium polysulfides (LiPSs) and inhibiting their shuttling. However, the intricate and interrelated microstructures pose a challenge in deciphering the correlation between the chemical environment surrounding the active site and its catalytic activity. Here, a novel SAC featuring a distinctive Mn‐N 3 ‐Cl moiety anchored on B, N co‐doped carbon nanotubes (MnN 3 Cl@BNC) is synthesized. Subsequently, the selective removal of the Cl ligands while inheriting other microstructures is performed to elucidate the effect of Cl coordination on catalytic activity. The Cl coordination effectively enhances the electron cloud density of the Mn‐N 3 ‐Cl moiety, reducing the band gap and increasing the adsorption capacity and redox kinetics of LiPSs. As a modified separator for Li–S batteries, MnN 3 Cl@BNC exhibits high capacities of 1384.1 and 743 mAh g −1 at 0.1 and 3C, with a decay rate of only 0.06% per cycle over 700 cycles at 1 C, which is much better than that of MnN 3 OH@BNC. This study reveals that Cl coordination positively contributes to improving the catalytic activity of the Mn‐N 3 ‐Cl moiety, providing a fresh perspective for the design of high‐performance SACs.