Light-Driven Fuel Cell with a 2D/3D Hierarchical CuS@MnS Z-Scheme Catalyst for H2O2 Generation

A photoelectrocatalytic (PEC) oxygen reduction reaction (ORR) strategy with fuel-efficient and cost-effective catalysts for on-demand hydrogen peroxide (H₂O₂) production is booming as an attractive alternative to the conventional anthraquinone process. Herein, we constructed a novel two-dimensional (2D)/three-dimensional (3D) hierarchical CuS@MnS p-p Z-scheme catalyst with full spectrum absorption and strong coupling interface by regulating the crystal structure, morphology, and photocharge transfer mechanism, which was used as a photocathode for PEC synthesis of H₂O₂ with a yield of 1.65 mM within 180 min. Taking advantage of a coupling strategy with Sn₃O₄/Ni foam, the as-prepared two-compartment cell with water oxidation reaction and ORR exhibited boosted activity and stability for the dual production of H₂O₂. An energy-saving H₂O₂ generation system was also constructed with a direct hydrazine/O₂ fuel cell, realizing the significant advantage in reducing electricity consumption during the H₂O₂ synthesis. Moreover, the onsite generation of H₂O₂ remarkably accelerated the degradation of pollutants via a cascade heterogeneous Fenton reaction with a Fe anode. This work provides a new strategy for designing a multifunctional PEC system for the production of high-value chemicals, energy recovery, and pollutant degradation.