化学
苯甲醇
苯甲醛
催化作用
脱质子化
吸附
光催化
可见光谱
酒精氧化
纳米颗粒
选择性
光化学
激进的
路易斯酸
吸收(声学)
无机化学
有机化学
纳米技术
材料科学
离子
复合材料
光电子学
作者
Yingzhang Shi,Mingchuang Shen,Zhiwen Wang,Cheng Liu,Jinhong Bi,Ling Wu
标识
DOI:10.1016/j.jcat.2023.01.015
摘要
Herein, a series of Pt nanoparticles modificatory Mn doped Bi4Ti3O12 ultrathin nanosheets (Pt/MnNS) are constructed as a surface functionalized photocatalyst for the visible-light-driven selective benzyl alcohol (BA) oxidation. Especially, Pt/5MnNS shows the best performance with a benzaldehyde (BD) yield rate of 1180 μmol·g−1·h−1 and a selectivity of 99.9 %. More importantly, experimental results reveal that Mn doping not only extends the optical absorption range of the photocatalyst to the visible region, but also induces the formation of more surface Ti4+δ atoms. Those Ti4+δ atoms as stronger Lewis acid centers achieve more conspicuous adsorption and activation of BA via the CO⋯Ti coordination. It makes the deprotonation of BA by photogenerated holes be easier. Meanwhile, Pt nanoparticles significantly promote the separation and transfer of the photogenerated carriers for supporting the formation of superoxide and carbon-centered radicals. Thus, the photocatalytic BA oxidation efficiency is markedly improved by surface multicomponent synergistic effect.
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