异质结
催化作用
电解质
氢
化学
动力学
无机化学
材料科学
化学工程
铂金
镍
电极
光电子学
物理化学
有机化学
工程类
物理
量子力学
作者
Liwei An,Shaofeng Deng,Xueshi Guo,Xupo Liu,Tonghui Zhao,Ke Chen,Ye Zhu,Yuxi Fu,Xu Zhao,Deli Wang
出处
期刊:Chinese Journal of Catalysis
[China Science Publishing & Media Ltd.]
日期:2022-12-01
卷期号:43 (12): 3154-3160
被引量:5
标识
DOI:10.1016/s1872-2067(22)64126-3
摘要
Nickel (Ni)-based materials act as one of the most promising candidates as platinum-group-metal-free (PGM-free) electrocatalysts for hydrogen oxidation reaction (HOR) in alkaline solution. Nevertheless, the electrocatalytic activity of pure Ni is significantly limited due to the sluggish kinetics under alkaline condition. To accelerate the kinetics, constructing heterostructures and nitride structures have been developed as two representative strategies. Here, we combined the two methods and presented a facile synthesis of the sheet-like Ni3N/MoO2 in-plane heterostructures for enhanced HOR in alkaline electrolytes. Relative to Ni or Ni3N, the Ni3N/MoO2 in-plane heterostructures exhibited a significantly increased mass activity by 8.6-fold or 4.4-fold, respectively. Mechanistic studies revealed that the enhanced activity of Ni3N/MoO2 could be attributed to the weakened hydrogen adsorption and strengthened hydroxyl adsorption. This work provides a facile approach to design high-efficiency catalysts for hydrogen-oxidation catalysis and beyond.
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