Green synthesis, optical and magnetic properties of a MnIImetal–organic framework (MOF) that exhibits high heat of H2adsorption

Green synthesis of a 3D, Mn(ii) MOF, [Mn₃(NDC)₃(DMA)₄]n(1) has been achieved by employing mechanochemical and sonochemical routes and1′exhibits an interesting gas uptake properties with a high value of isosteric heat of adsorption (Q_st) for H₂.