离子液体
电解质
溶剂化
化学
电化学
相间
锂(药物)
取代基
烷基
无机化学
阳离子聚合
咪唑
化学工程
离子
高分子化学
有机化学
物理化学
电极
催化作用
医学
遗传学
内分泌学
工程类
生物
作者
Shihan Qi,Jiandong Liu,Jian He,Huaping Wang,Mingguang Wu,Daxiong Wu,Junda Huang,Fang Li,Xin Li,Yurong Ren,Jianmin Ma
标识
DOI:10.1016/j.jechem.2021.05.040
摘要
Electrolyte chemistry offers the opportunity to regulate the solid electrolyte interphase (SEI) and Li+ solvation, which is considered to be crucial to the growth of lithium crystals for safe lithium metal batteries (LMBs). Structurally tunable characteristics of ionic liquids (ILs) from anion type, cationic substituent chain length and cationic substituents, will contribute this field. Here, we explore the influence mechanism of imidazole-based ILs as electrolyte additives on Li+ solvation and the formation of SEI. ILs can participate into the formation of efficient SEI, together with cathode electrolyte interphase (CEI). Moreover, ILs can also regulate the sheath structure of Li+ solvation, to fasten the kinetics of Li. Furthermore, the imidazole-based cations with long alkyl chain can form an electrostatic shield around newly formed Li nucleus, and suppress further Li plating at this site. Under the optimized condition, the 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([OMIm]TFSI) additive shows the best ability to enhance the electrochemical performance, endowing the Li||Li symmetric cell with a stable life (over 800 h) at 0.5 mA cm−2 and the Li||LiNi0.6Mn0.2Co0.2O2 (NMC622) full cell with a high capacity of 141.7 mAh g−1 after 200 cycles at 0.5 C.
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