Type I ‘Lighted Metal‐free’ Photosensitizing Assemblies of Phenazine for Aerobic Oxidative Transformations

Highly photostable supramolecular photosensitizing 'lighted metal-free' assemblies of DPZ-Th have been developed which show strong absorption in the visible region and excellent electron transportation potential from donor to acceptor units. The as-prepared assemblies of DPZ-Th activate aerial oxygen to generate Type I reactive oxygen species (ROS) under visible-light irradiation in mixed aqueous media. Owing to these properties, the as-prepared DPZ-Th assemblies exhibit high photocatalytic activity in catalyzing the aerobic oxidative coupling of benzylamines and synthesis of quinazolines. Various spectroscopic studies support the participation of Type I reactive species in the reaction mechanism. The 'pure' oxygen environment was not needed for carrying out these transformations and all the reactions proceed very well under aerial conditions to furnish the desired products in high yields.