材料科学
阴极
钾
离子
相变
相(物质)
雅恩-泰勒效应
衍射
吸收(声学)
化学工程
化学物理
复合材料
热力学
物理化学
冶金
化学
光学
有机化学
物理
工程类
作者
Rui-Jie Luo,Xun‐Lu Li,Jieying Ding,Jian Bao,Cui Ma,Chong‐Yu Du,Xin-Yin Cai,Xiaojing Wu,Yong‐Ning Zhou
标识
DOI:10.1016/j.ensm.2022.02.027
摘要
In the development of cathode materials for potassium-ion batteries, K0.5MnO2 cathode has shown great potential due to its high capacity and high energy density. However, it suffers from poor cycle stability due to the strong Jahn-Teller effect of Mn3+ and structure degradation. Here, by introducing Mg into the potassium layer, we design a new layered P3-type K0.5Mg0.15[Mn0.8Mg0.05]O2 cathode material. By using X-ray diffraction and absorption techniques, it is revealed that Mg ions in potassium layer can not only suppress the Jahn-Teller effect and prevent phase transition effectively, but also enhance the kinetics and thermodynamic properties of the cathode materials, thus greatly improve the cycle stability and rate capability. The strategy may open a new opportunity to design layered cathode materials for high performance potassium-ion batteries.
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