吸附
硫酸盐
零电荷点
化学
无机化学
滴定法
氧化还原
氧化物矿物
基础(拓扑)
Zeta电位
磁铁矿
内球面电子转移
氧化物
酸碱滴定法
离子强度
吸附
离子
水溶液
化学工程
纳米颗粒
物理化学
化学反应
材料科学
有机化学
冶金
数学分析
工程类
数学
作者
C. Mansour,Grégory Lefèvre,E.M. Pavageau,H. Catalette,M. Fédoroff,Sandrine Zanna
标识
DOI:10.1016/j.jcis.2008.11.009
摘要
In order to acquire data necessary to understand and predict the behavior of oxide particles in the secondary circuits of pressurized water reactors (PWR) and study the role of redox and interface reactions, the acid-base properties of magnetite and sorption of sulfate ions were studied at 25 degrees C. Redox reactions with magnetite predicted from thermodynamic data were not observed and sulfur species always remain as sulfate. From zetametric measurements, mass titrations and acid-base titrations an IEP at 6.7 and a PZC at 6.2 were found. Acid-base experimental data were modeled in the 2pK surface complexation model in CCM or BSM. Sulfate sorption increase with decreasing pH is typical for anionic species on oxides. For the modeling of sorption data, the choice of surface species was guided by the slope of the sorption curves and by the evolution of zeta potential. In the proposed model, sulfate ions are sorbed essentially as outer-sphere complexes, with a partial sorption as a neutral bidentate inner-sphere complex below pH 5.
科研通智能强力驱动
Strongly Powered by AbleSci AI