对映选择合成
非对映体
亲核细胞
化学
转化(遗传学)
手性助剂
形式综合
立体化学
铃木反应
光学活性
组合化学
有机化学
催化作用
钯
生物化学
基因
作者
H.-Y.A. Yim,H. N. C. Wong
摘要
The addition reactions of various nucleophiles to a furyl sulfonylimine bearing a chiral boronate at the C-3 position furnished chromatographically separable diastereomers. The R diastereoselection was found to be more favorable. Further transformation of C-B bonds to C-C bonds was achieved by using standard Suzuki coupling conditions to give optically active 2,3-disubstituted furyl sulfonylamides.
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