动力学同位素效应
氘
化学
动能
同位素
口译(哲学)
键裂
计算化学
热力学
有机化学
催化作用
原子物理学
核物理学
物理
计算机科学
量子力学
程序设计语言
作者
Eric M. Simmons,John F. Hartwig
标识
DOI:10.1002/anie.201107334
摘要
Rate versus selectivity determining: The measurement of a kinetic isotope effect (KIE) can provide valuable information about the mechanism of a reaction, but care must be taken in the design and interpretation of KIE experiments. Depending on the experiment that is conducted, the observation of a primary KIE resulting from H/D substitution does not necessarily imply that CH bond cleavage occurs during the rate-determining step of a reaction. FG=functional group.
科研通智能强力驱动
Strongly Powered by AbleSci AI