材料科学
石墨
相(物质)
钒
结构精修
电阻率和电导率
金属
氧化钒
衍射
铝
分析化学(期刊)
氧化物
大气温度范围
碳纤维
化学工程
冶金
复合材料
化学
热力学
光学
有机化学
工程类
物理
电气工程
复合数
色谱法
作者
В. А. Горшков,А. В. Карпов,D. Yu. Kovalev,А. Е. Сычев
标识
DOI:10.1134/s0031918x20080037
摘要
Abstract–A material based on the V2AlC MAX phase has been obtained for the first time by the method of self-propagating high-temperature synthesis (SHS) using a reaction mixture of vanadium oxide(V) and (IV) powders with aluminum and carbon (graphite). The obtained material was characterized by X-ray diffraction and energy-dispersive X-ray spectroscopy. The Rietveld method was used to perform quantitative analysis. The synthesized material based on the V2AlC MAX phase is an electrical conductor that demonstrates the metallic behavior of conductivity in the entire measured temperature range of 300–1300 K in the vacuum of 2 × 10–3 Pa. It has been suggested that the V2AlC phase makes a decisive contribution to the electrical resistance of the synthesized material that may be caused by the formation of V2AlC nanolaminate grains contacting with each other in the bulk of the material.
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