沸石咪唑盐骨架
材料科学
甲醇
咪唑酯
化学工程
晶体工程
溶剂热合成
金属有机骨架
纳米技术
晶体结构
结晶学
有机化学
物理化学
化学
吸附
工程类
超分子化学
作者
Daixiong Zhang,Qing Xiang
标识
DOI:10.1016/j.matlet.2021.129418
摘要
As one of most studied MOFs, extensive efforts have been devoted on the novel strategy for tailoring the size of zeolitic imidazolate framework (ZIF-8). We report here a facile and general method that enables the size-controllable engineering of zeolitic imidazolate framework (ZIF-8) by changing the addition order of Zn(NO3)2·6H2O (A) and 2-methylimidazole (B), which is very different from the all reported methods. Significant size difference for ZIF-8 s was observed between adding A-methanol solution to B-methanol solution and adding B-methanol solution to A-methanol solution under room temperature magnetic stirring. The influence of addition order on the crystal size was also applicable for preparing ZIF-8 encapsulating metal precursor (M-ZIF-8). We believe that this work not only pave a new way for efficient and general size-controllable design of ZIF-8 and M-ZIF-8, but can be also bridged with other size engineering methods (such as solvothermal method).
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