Characterization of Porous Titanium-Hydroxyapatite Composite Biological Coating on Polyetheretherketone (PEEK) by Vacuum Plasma Spraying

Titanium powders and hydroxyapatite powders were used to fabricate the titanium and hydroxyapatite composite coating (Ti/Ti/HA) on the Polyetheretherketone (PEEK) by vacuum plasma spraying (VPS). The phase composition and morphology of the Ti/Ti/HA coating were analyzed by XRD, SEM, industrial CT, and three-dimensional contour profiler (DEKTAK XT). The results showed that the phase composition of the Ti/Ti/HA coating was dominated by the HA phase and a small amount of the Ti phase. The Ti/Ti/HA composite coating presented an obvious three-layer structure with different roughness and porosity. The bottom was Ti coating with a porosity less than 10%; the middle was porous Ti coating with a porosity of 35% ± 10%; the surface coating was HA coating with the crystallinity near 95%, a porosity of 32% ± 10%, a roughness Ra = 30 ± 10 μm. Moreover, the TG-DSC and ATR-FTIR results showed that VPS coating has no effect on thermochemical properties of PEEK material. The average bond strength of the composite coating was achieved 32 MPa.