Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room‐Temperature Sodium‐Ion Batteries

Advanced Energy MaterialsVolume 3, Issue 2 p. 156-160 Communication Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries Zelang Jian, Zelang Jian Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSearch for more papers by this authorWenze Han, Wenze Han Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China China Institute of Atomic Energy, Beijing 102413, ChinaSearch for more papers by this authorXia Lu, Xia Lu Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this authorHuaixin Yang, Huaixin Yang Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this authorYong-Sheng Hu, Corresponding Author Yong-Sheng Hu [email protected] Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Yong-Sheng Hu, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Wen Chen, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Dongfeng Chen, China Institute of Atomic Energy, Beijing 102413, China.Search for more papers by this authorJing Zhou, Jing Zhou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSearch for more papers by this authorZhibin Zhou, Zhibin Zhou School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaSearch for more papers by this authorJianqi Li, Jianqi Li Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this authorWen Chen, Corresponding Author Wen Chen [email protected] State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Yong-Sheng Hu, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Wen Chen, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Dongfeng Chen, China Institute of Atomic Energy, Beijing 102413, China.Search for more papers by this authorDongfeng Chen, Corresponding Author Dongfeng Chen [email protected] China Institute of Atomic Energy, Beijing 102413, China Yong-Sheng Hu, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Wen Chen, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Dongfeng Chen, China Institute of Atomic Energy, Beijing 102413, China.Search for more papers by this authorLiquan Chen, Liquan Chen Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this author Zelang Jian, Zelang Jian Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSearch for more papers by this authorWenze Han, Wenze Han Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China China Institute of Atomic Energy, Beijing 102413, ChinaSearch for more papers by this authorXia Lu, Xia Lu Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this authorHuaixin Yang, Huaixin Yang Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this authorYong-Sheng Hu, Corresponding Author Yong-Sheng Hu [email protected] Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Yong-Sheng Hu, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Wen Chen, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Dongfeng Chen, China Institute of Atomic Energy, Beijing 102413, China.Search for more papers by this authorJing Zhou, Jing Zhou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSearch for more papers by this authorZhibin Zhou, Zhibin Zhou School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaSearch for more papers by this authorJianqi Li, Jianqi Li Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this authorWen Chen, Corresponding Author Wen Chen [email protected] State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Yong-Sheng Hu, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Wen Chen, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Dongfeng Chen, China Institute of Atomic Energy, Beijing 102413, China.Search for more papers by this authorDongfeng Chen, Corresponding Author Dongfeng Chen [email protected] China Institute of Atomic Energy, Beijing 102413, China Yong-Sheng Hu, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Wen Chen, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China Dongfeng Chen, China Institute of Atomic Energy, Beijing 102413, China.Search for more papers by this authorLiquan Chen, Liquan Chen Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, ChinaSearch for more papers by this author First published: 23 October 2012 https://doi.org/10.1002/aenm.201200558Citations: 741Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link 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Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract A Na3V2(PO4)3/C composite with 3.8 wt.% carbon, which was synthesized by a one-step solid state reaction, exhibits Na storage capacity of 107 mAh g−1 and high coulombic efficiency of 99.8% in a new NaFSI/PC electrolyte. In situ XRD results reveal its sodium storage mechanism as a typical two-phase reaction from the Na3V2(PO4)3 to NaV2(PO4)3 phases with 8.26% volume variation. These desired properties make it very promising for application in room-temperature sodium- ion batteries. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description aenm_201200558_sm_suppl.pdf368.3 KB suppl Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume3, Issue2February, 2013Pages 156-160 RelatedInformation